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Most cats love to be scratched behind the ears. This is a good reward for giving a kiss.
Some cats, especially those that have been abused, will occasionally snap at their human companions. Proceed with caution.
It's hard to look at an adorable pussy cat and not feel a rush of love and affection. That said, cats do not have the reputation for being "kissey" creatures. However, like most other animals, they can be trained.
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How to Train Your Cat to Give Kisses
Place some cream cheese or baby food on your finger or cheek.
Call your cat. Point you your face or finger and say "kiss."
Praise your cat by petting him and giving him a cat treat. Eventually, your cat will discover that he actually enjoys kisses.